Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate
نویسندگان
چکیده
منابع مشابه
Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate
In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetra-hedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (-) anions and three uncoordinated CH(3)CN solvent mol-ecules. The three anions are disordered over two sites through a rotation along one of the F-P-F axes. The relative occupancies of the two sites for the F atoms are 0.643...
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The acetonitrile ligand in the title compound, [W(CH(3)CN)(CO)(5)], is coordinated end-on to a penta-carbonyl-tungsten(0) fragment with a W-N bond length of 2.186 (4) Å, completing an octa-hedral coordination environment around the W atom.
متن کامل2-(2-Nitrophenylsulfinyl)acetonitrile
In the title compound, C8H6N2O3S, the dihedral angle between the nitro group and the benzene ring is 6.76 (9)°. The bond-angle sum at the S atom is 308.1°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds to generate (010) sheets. The crystal studied was found to be a racemic twin.
متن کامل(1-Bromonaphthalen-2-yl)acetonitrile
The title compound, C(12)H(8)BrN, was prepared as a starting material for a Suzuki cross-coupling reaction with a pinacol ester. The torsion angle about the ring-methylene C-C bond is 30.7 (3)°, such that the N atom is displaced by 1.174 (4) Å from the plane of the naphthalene ring system.
متن کامل2-[4-(Methylsulfonyl)phenyl]acetonitrile
In the title compound, C(9)H(9)NO(2)S, the benzene ring and the acetonitrile group are approximately coplanar, with a C-C-C-C torsion angle of 1.1 (3)° between them. In the crystal, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds into layers parallel to (001).
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ژورنال
عنوان ژورنال: IUCrData
سال: 2018
ISSN: 2414-3146
DOI: 10.1107/s241431461800528x